Not a movie but a documentary. On Any Sunday covers a lot of his motorcycle racing career. He raced under made up names because it was a violation of his movie contracts to race like he did.
Dunno. It'd be Bullitt, The Great Escape, or The Magnificent Seven. Maybe Seven just because he spends half his time subtly upstaging Yul Brynner, but it's hard to beat the chase scene in Bullitt.